Dielectric relaxation measurements on ethyl acrylate-alcohol (1-propanol, 1-butanol, 1-hexanol, and 1-octanol) mixtures for different concentrations over the frequency range 10 MHz-10 GHz have been carried out using time domain reflectometry. Parameters such as the static permittivity, dielectric relaxation time, the Kirkwood correlation factor, and the excess inverse relaxation time were determined and discussed to yield information on the molecular structure and dynamics of the mixture. The values of the dielectric properties decrease with increased ethyl acrylate concentration in alcohol and systematically vary with the alkyl chain length of alcohols. The excess inverse relaxation time values are found to be negative for all concentrations, it may indicate that the effective dipoles of the system rotate slowly.