I. INTRODUCTIONDue to their intrinsic merits including non/less-invasive virtue and capability of automation and remote sensing, geophysical electromagnetic (EM) methods such as time domain reflectometry (TDR) [1] and ground penetrating radar (GPR) [2] have long been recognized as effective and practical methods in geomaterials characterization [3], [4]. Generally measuring time or frequency dependent EM properties of geomaterials as response to an applied EM field, EM methods are able to characterize geomaterials in terms of correlations between their EM properties and compositional and structural properties. Successful applications of EM methods in this regard have been massively witnessed since decades ago, among which the determination of water content of geomaterials is probably the most well-known one [5].Despite its great success, the application of EM methods in geomaterials characterization is still confronted with many theoretical and technical difficulties. Almost all geomaterials are heterogeneous systems composed of components with different physicochemical properties. Complex EM properties of some constituent components in addition to interface processes arising from the interaction between those components make the overall EM properties of most geomaterials extremely complicated. Theoretical consideration on their EM properties is greatly challenged by this complication because it is difficult to take all factors into account. However, carefully designed experimental studies are able to determine factors that dominate the EM properties of geomaterial at defined environments and thereby able to greatly simplify and/or optimize theoretical consideration. Experimental studies, especially in a broad frequency range, are also able to find out correlations between EM properties and other engineering parameters of geomaterials, which are practical in field investigation.On the other hand, EM properties of a geomaterial are generally affected by a great number of factors related to environmental parameters as well as its compositional and structural nature. For civil engineering purposes, it is intended to measure EM properties of geomaterials without disturbing their engineering nature. Optimized measurement protocol in combination with non-destructive sample cells is therefore highly desirable to this end. Open-ended coaxial probe (OC) has long been used as a non-destructive sample cell in the characterization of various materials including biological tissues [6], [7], liquids [8]-[10], and geomaterials [11]-[14]. Since the sample under test has to be fully contacted with the flat end of this type of probe, it is generally only suitable for soft materials or hard materials with ideally flat surface. In addition, due to the size of this type of probe, the effective measurement volume is normally limited to the order of cm 3 . A non-destructive two-port coaxial transmission line cell (CC) recently developed by Lauer et al. [15] is able to measure a larger sample volume but still keep the sample undistur...