“…The electrical conductivity in La 1Àx A x FeO 3Àd (A = Ca, Sr, Ba) and related perovskite oxides is commonly interpreted on the basis of hopping of small polarons. 26,[40][41][42] Under oxidizing atmospheres, the conductivity can be expressed as, 26,43 s…”
Revisiting the electrical conduction and oxygen transport properties of alkaline-earth metal substituted La0.6A0.4FeO3−δ (A = Ca, Sr and Ba) perovskite oxides.
“…The electrical conductivity in La 1Àx A x FeO 3Àd (A = Ca, Sr, Ba) and related perovskite oxides is commonly interpreted on the basis of hopping of small polarons. 26,[40][41][42] Under oxidizing atmospheres, the conductivity can be expressed as, 26,43 s…”
Revisiting the electrical conduction and oxygen transport properties of alkaline-earth metal substituted La0.6A0.4FeO3−δ (A = Ca, Sr and Ba) perovskite oxides.
“…A decrease in ε΄ with increasing frequency is due to the fact the dipole lags behind the applied field at higher frequencies. The decrease of ε΄ with increasing frequency as observed for LTNO materials is a typical dielectric behavior seen in many of the traditional dielectrics with a high dielectric constant [2][3][4]11]. At room temperature, the values of ε΄ (at 100 Hz) in Li,Ti codoped NiO compounds are exceedingly higher (~10 5 ) than that of pure NiO (~900).…”
Section: Nickel-based Multi-component Oxide Ceramics Have Been the Rmentioning
confidence: 81%
“…Simple and multi-component oxide dielectrics play key role in a wide variety of current and emerging technologies [1][2][3][4][5]. While there has been a great deal of interest in the wide band gap oxide materials for electronics, electro-optics, opto-electronics and magneto-electronics, a special attention is drawn in recent years towards the materials with high and/or giant dielectric constant for their expected revolutionary applications in micro/nano-electronics industry [1][2][3][4][5][6]. Such materials will have enormous applications in electrical storage and electronic data processing devices.…”
Tuning the dielectric properties via composition-tailoring is demonstrated for variablelithium, constant-titanium co-doped nickel oxide (LixTi0.1Ni1-xO; x=0.05-0.30; referred to LTNO).. The effect of variable Li-content on the structure and dielectric properties of LTNO is investigated. X-ray diffraction studies confirm the formation of a cubic NiO phase in LTNO for x=0.05-0.30. However, lattice parameter reduction was evident with increasing Li-content. Composition-driven giant dielectric constant (10 4-10 5) was observed for a higher lithium content (x=0.15-0.30) leading to realization of LTNO ceramics. The origin of the high dielectric constant observed in these low density LTNO ceramics is attributed to the Maxwell-Wagner polarization mechanism.
“…For example, the insertion of Ca into the Asite, reported by Andoulsi et al 14 and by Shi et al, 15 reduced the electrical resistance and improved the magnetic properties. Also, Benali et al 16 studied the effect of the introduction of lead cations in the A-site of the compound La 0.8 Ca 0.1 FeO 3 , on the structural, dielectric and gas detection properties. They found that insertion of the Pb ion into the A-site can restrict grain size growth and improve the response to ethanol gas.…”
This work involves the synthesis and study of physical properties of the La0.8Ca0.1Pb0.1Fe0.975Mg0.025O3 compound, which has been characterized by various experimental techniques, such as X-ray diffraction, SEM and complex impedance spectroscopy.
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