In this study, dielectric constants (D
k) and dissipation factors (D
f) of 15
types of polyimides (PIs), including wholly aromatic, semialicyclic,
partially fluorinated, and perfluorinated PIs, were measured in the
transverse electric (TE011) mode at a frequency of 10 GHz
and analyzed based on their chemical structures and the dominant factors
of dielectric polarization per unit volume (P
t). The relationships among the dipolar orientational (P
d) and electronic (P
e) polarizations and dielectric properties (D
k and D
f) were quantitatively investigated.
Although a systematic correlation between the structure and D
f of PIs has not yet been established, we found
that the D
f of PIs is anisotropic and
linearly proportional to P
d in the in-plane
direction, which can be estimated from the D
k and in-plane refractive index (n
TE) at 1310 nm. This could be related to the bidirectional relationship
between the real (D
k) and imaginary (D
f) parts of the relative permittivity. Furthermore,
the D
k and D
f of all PIs increased linearly with respect to the relative humidity
(RH) of the measurement environment, and their slopes (h
Dk and h
Df), i.e., the RH
sensitivities of D
k and D
f, showed a proportional relationship with a high correlation
coefficient (R
2 = 0.986). The weight fraction
of polar imide and ester groups (Polar %) and the hydrophobicity of
PIs, which are closely related to the fluorine content (F %), are essential factors in determining the values of D
k, D
f, h
Dk, and h
Df. These relationships
are crucial for developing low-dielectric PI materials exhibiting
low D
k and D
f values, as well as reduced sensitivity to humidity.