1996
DOI: 10.1016/0016-2361(95)00300-2
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Diesel combustion of an alkylated polycyclic aromatic hydrocarbon

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Cited by 17 publications
(11 citation statements)
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“…Substituted benzenes are recognized to play an important role in the pathways to larger polyaromatic hydrocarbons (PAHs) in combustion engines and more generally in flames. , The chemical complexity of many of the substituted aromatics in fuels and fuel-rich flames necessarily opens the possibility for structural and conformational isomers. One anticipates that different structural isomers could have substantially different chemical reactivity, particularly in their abilities to form larger PAH molecules.…”
Section: Introductionmentioning
confidence: 99%
“…Substituted benzenes are recognized to play an important role in the pathways to larger polyaromatic hydrocarbons (PAHs) in combustion engines and more generally in flames. , The chemical complexity of many of the substituted aromatics in fuels and fuel-rich flames necessarily opens the possibility for structural and conformational isomers. One anticipates that different structural isomers could have substantially different chemical reactivity, particularly in their abilities to form larger PAH molecules.…”
Section: Introductionmentioning
confidence: 99%
“…Combustion models face a daunting task as they seek to describe the complex array of reactions that produce and destroy aromatics and polyaromatic hydrocarbons in flames and combustion engines. Most experimental studies have rightly approached this task by studying flames involving a single fuel or a single fuel doped by a single additive. ,, However, combustion engines burn gasoline or diesel fuels, which are not single-component fuels but instead are complicated mixtures of hydrocarbons and additives including significant fractions of alkylbenzenes of various chain lengths. Since aromatic molecules are important precursors to soot formation, the incomplete combustion of these aromatic derivatives has been shown to be responsible for a substantial fraction of the soot/particle formation in automobile exhaust …”
Section: Introductionmentioning
confidence: 99%
“…Since aromatic molecules are important precursors to soot formation, the incomplete combustion of these aromatic derivatives has been shown to be responsible for a substantial fraction of the soot/ particle formation in automobile exhaust. 11 Whatever their original source, substituted benzenes clearly play an important role in the pathways to larger PAH molecules in combustion engines and more generally in flames. 11,12 The chemical complexity of many of the substituted aromatics in fuels and fuel-rich flames necessarily opens the possibility for structural and conformational isomers.…”
Section: Introductionmentioning
confidence: 99%
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“…Substituted benzenes play an important role in the pathways to larger PAH molecules in fuel combustion processes. , The chemical complexity of many of the substituted aromatics in fuels and fuel-rich flames opens the possibility for structural and conformational isomers. Different structural isomers can have substantially different chemical reactivity .…”
Section: Introductionmentioning
confidence: 99%