Throughout their lifetime, adults learn new words in their native lannguage, and potentially also in a second language. However, they do so with variable levels of success. In the auditory word learning literature, some of this variability has been attributed to phonological skills, including decoding and phonological short-term memory. Here I examine how the relationship between phonological skills and word learning applies to the visual modality. I define the availability of phonology in terms of (1) the extent to which it is biased by the learning environment, (2) the characteristics of the words to be learned, and (3) individual differences in phonological skills. Across these three areas of research, visual word learning improves when phonology is made more available to adult learners, suggesting that phonology can facilitate learning across modalities. However, the facilitation is largely specific to alphabetic languages, which have predictable sublexical correspondences between orthography and phonology. Therefore, I propose that phonology bootstraps visual word learning by providing a secondary code that constrains and refines developing orthographic representations. Keywords Adult word learning. Orthographic processing. Phonological recoding. Lexical quality Adults continually learn new words in their native language (L1), and possibly also in a second language (L2), making vocabulary one of the few aspects of language that continues to expand throughout the lifespan (e.g., Ramscar, Hendrix, Shaoul, Milin, & Baayen, 2014; Verhaeghen, 2003). Establishing a rich vocabulary is a key prerequisite for success in areas as varied as reading comprehension, syntax development, and foreign language proficiency (e.g., Meschyan & Hernandez, 2002; Ricketts, Nation, & Bishop, 2007). Whereas learning new words comes easy to some, it is a challenge for others, and the factors that underlie this variability remain poorly understood. Building on the growing evidence that strong phonological abilities improve the acquisition of new auditory word forms (e.g.