Electrostatic cleanliness requirements on ISEE 1 were expected to prevent negative charging in sunlight. This has largely been true, but on three occasions, ISEE 1 has been observed to charge to significant negative potentials in sunlight. Data from the two electric field experiments and from the plasma composition experiment on ISEE 1 show that the spacecraft charged to close to -70 V in sunlight at about 0700 UT on March 17, 1978. Data from the electron spectrometer experiment show that there was a potential barrier of some -10 to -20 V about the spacecraft during this event. The potential barrier was effective in turning back emitted photoelectrons to the spacecraft. Potential barriers can be formed by differential charging on the spacecraft or by the presence of excess space charge in the plasma. The shape of the barrier suggests that it is due to the former, even though electrostatic cleanliness specifications imposed on ISEE were intended to eliminate differential charging. Modeling of this event showed that the barrier could not be produced by the presence of space charge but that it was most likely produced by differential charging of the solar arrays. ISEE and GEOS, have experienced. much smaller potentials, e.g., +1 to +50 for ISEE in sunlight and +1 to +10 for GEOS in sunlight [Wrenn, 1979' Wrenn et al., 1979Whipple, 1981]. The electrostatic specifications for ISEE required that no exposed components (with some exceptions) charge to potentials in excess of 1 V with respect to the spacecraft ground. Also, all components exposed to the, plasma environment were to be "sufficien•tly conducting" and be connected to the spacecraft ground through low impedance paths.In spite of these electrostatic cleanliness requirements and ß general success in controlling negative charging, there have been indications of significant charging events on ISEE 1, with the spacecraft reaching a negative potential of the order of -100 V in sunlight. These indications initially came from ion data obtained by the plasma composition experiment which showed that low-energy (thermal) ions had been accelerated to kinetic energies of the order of 100 eV before they were detected by the instrument (E. Shelley, private communication, 1982). It is important to understand such charging events, if they are indeed real, in order to be able to evaluate the effectiveness of the electrostatic cleanliness specifications. For example, the charging of electrostatically "dirty" spacecraft such as ATS 5, ATS 6, and SCATHA has been shown to be very dependent on differential charging effects [Olsen et al., 1981' Olsen and Purvis, 1983]. The purpose of this paper is to examine in detail a sunlight cha•ging event on ISEE 1 and to determine if differential charging occurred in spite of the electrostatic cleanliness requirements. 5568