The pore structure
of organic matter (OM) is affected by the maturity
and type of OM, and these exert an important control on the development
of OM pores. However, it is often challenging to distinguish between
autochthonous and secondary OM. In this study, different types of
OM were distinguished by means of morphology and the form of its occurrence
under scanning electron microscopy (SEM) observation. Pyrolyzed samples
were used to obtain pore structures of autochthonous and secondary
OM from a lacustrine shale from high to over mature stages. The SEM
observations indicated that the secondary OM is porous, whereas the
autochthonous OM is nonporous. Further, nitrogen adsorption data showed
that nanopores in the autochthonous OM are blocked in non-extracted
samples and reoccurred after extraction, whereas nanopores in the
secondary OM remain open from high to over mature stages. Moreover,
the pore structure, i.e., pore type and pore size, differed for autochthonous
and secondary OM in the lacustrine shale. For instance, nanopores
in the autochthonous OM were micropores (smaller than 1.5 nm); nanopores
in the secondary OM were mesopores (ranging from 5 to 20 nm) and micropores.
Nanopores in the autochthonous OM were formed at reflectance values
(Ro) of 1.50%, but they were slightly destroyed at the over mature
stage. Nanopores in the secondary OM were formed at 2.00% Ro and were
preserved. Therefore, the development of OM nanopores in the lacustrine
shale was synchronously affected by the type of OM and maturity. Furthermore,
nanopores in the secondary OM were more developed than those in the
autochthonous OM; thus, the OM nanopores at the high mature stage
belonged to the autochthonous OM, and those at the over mature stage
mainly belonged to the secondary OM. Besides, the nanopores in the
autochthonous OM are easily blocked. Therefore, the secondary OM is
important to the development of OM nanopores in the lacustrine shale
at the over mature stage.