2007
DOI: 10.1021/jp076835e
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Difficulties in Building Radiation-Generated Three-Spin Systems Using Spin-Labeled Luminophores

Abstract: Aromatic compounds are well-known acceptors of primary radical ions that are formed under high-energy irradiation of nonpolar systems. Thus formed radical ion pairs recombine and produce magnetosensitive fluorescence, which helps study the short-lived radical ions. It was initially suggested that a simple introduction of a spin label into the original arene would allow an easy transition from two-spin to three-spin systems, retaining the experimental techniques available for radical pairs. However, it turned o… Show more

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