We show convergence of the Navier–Stokes/Allen–Cahn system to a classical sharp interface model for the two-phase flow of two viscous incompressible fluids with same viscosities in a smooth bounded domain in two and three space dimensions as long as a smooth solution of the limit system exists. Moreover, we obtain error estimates with the aid of a relative entropy method. Our results hold provided that the mobility $$m_\varepsilon >0$$
m
ε
>
0
in the Allen–Cahn equation tends to zero in a subcritical way, i.e., $$m_\varepsilon = m_0 \varepsilon ^\beta $$
m
ε
=
m
0
ε
β
for some $$\beta \in (0,2)$$
β
∈
(
0
,
2
)
and $$m_0>0$$
m
0
>
0
. The proof proceeds by showing via a relative entropy argument that the solution to the Navier–Stokes/Allen–Cahn system remains close to the solution of a perturbed version of the two-phase flow problem, augmented by an extra mean curvature flow term $$m_\varepsilon H_{\Gamma _t}$$
m
ε
H
Γ
t
in the interface motion. In a second step, it is easy to see that the solution to the perturbed problem is close to the original two-phase flow.