“…The emission maxima and quantum yields in PMMA matrices (Table ) are only marginally sensitive to complex concentration (spectra shown in the Supporting Information), even though platinum(II) complexes can potentially interact through coplanar stacking. Consequently, the energy of the highest occupied molecular orbital (HOMO) is raised and the energy of the lowest unoccupied molecular orbital (LUMO) is reduced, resulting in a bathochromic shift of emission bands , . Instead, we do not observe such marked concentration‐dependent excimer formation and ascribe the slight redshifts to changes in the polarity of the environment.…”