Digital Camera System in Transmission Electron Microscope

Han, Cheolsu; Jeung, Jong-Man; Kim, Jin-Gyu; Lee, Sangchul

doi:10.1017/s1431927619003465

Cited by 2 publications

(3 citation statements)

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“…TEM is a powerful tool in nanometer science and technology and broadly used to observe the lamellar structure of specimens by transmitting an accelerated electron beam through the thin specimen and magnifying and visualizing it with several electromagnetic lenses . Consequently, it is frequently utilized to characterize the hierarchical structure of core–shell nanofibers. − The mixed solutions PEU and PCL were directly electrospun onto the copper grid and imaged by TEM.…”

Section: Resultsmentioning

confidence: 99%

Preparation and Evaluation of Core–Shell Nanofibers Electrospun from PEU and PCL Blends via a Single-Nozzle Spinneret

Fang

Zhang

Wang

et al. 2023

ACS Appl. Polym. Mater.

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The core−shell structured nanofibers are routinely fabricated by coaxial solution and single-nozzle emulsion electrospinning of two polymers. Herein, the core−shell structured polymeric nanofibers were electrospun from mixed solutions of poly(ether urethane) (PEU) with poly(ε-caprolactone) (PCL) or other biodegradable aliphatic polyesters via a single-nozzle spinneret. For comparison, the mixed solutions electrospinning of poly(carbonate urethane) (PCU) with these polyesters including PCL was also conducted. The morphologies and hierarchical structures of the as-spun nanofibers were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), in vitro lipase degradation, differential scanning calorimeter (DSC), and Fourier-transform infrared (FTIR) analyses. It was shown that the blends of PEU with PCL or other biodegradable aliphatic polyesters were solely electrospun into the core−shell structured nanofibers with PEU as a shell and PCL or other biodegradable aliphatic polyesters as a core. The thickness of core/shell layers from 833/606 to 193.3/54.2 μm was adjustable by varying the feeding mass ratio from 1:3 to 3:1 of PEU to PCL or other biodegradable aliphatic polyesters. In DSC analysis, the T onset of PEU@PCL core−shell fiber was 1.31 °C higher than that of the PCL fiber, while T m was approximate. Furthermore, changing the electrospinning solvents of PEU with PCL or other biodegradable aliphatic polyesters retained the formation of core−shell nanofibers. In contrast, the blends of PCU with these polyesters tended to form co-continuous structured nanofibers. The effects of the physicochemical properties of mixed solutions on the charged liquid droplets, whipped jets, and morphology of the electrospun nanofibers were also inspected. The creation of core−shell nanofibers from the blends of PEU with PCL or other biodegradable aliphatic polyesters was most likely due to the interaction between the inherent thermodynamic phase separation of the polymers and their external stretching kinetic phase separation during electrospinning.

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Section: Resultsmentioning

confidence: 99%

Preparation and Evaluation of Core–Shell Nanofibers Electrospun from PEU and PCL Blends via a Single-Nozzle Spinneret

Fang

Zhang

Wang

et al. 2023

ACS Appl. Polym. Mater.

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show abstract

“…25 The current ETEM operates by employing differential pumping apertures to confine gases to the high pressure region around the sample and connecting an external pump to the microscope column (Fig. 2a and b), 19,26 This setup enables the capture of atomic scale images, with gas pressures typically below 10 Torr and time resolutions reaching up to 1 ms. 27,28 Compared to other in situ systems, the windowed holder (gas reaction system) enables material characterization in a gas and heating environment within a traditional TEM (as shown in Fig. 2c and Table 2).…”

Section: In Situ Tem Technologiesmentioning

confidence: 99%