2016
DOI: 10.1002/slct.201601216
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Diiron Complexes [Fe2(CO)5(μ‐pdt/Mebdt)(L)] Containing a Chelating Diphosphine Ligand L=(Oxydi‐2,1‐phenylene)bis(diphenylphosphine): Bioinspired [FeFe] Hydrogenase Model Complexes

Abstract: Diiron carbonyl complexes [Fe 2 (CO) 5 (m-pdt)(k 1 -L)] 1 and [Fe 2 (CO) 5 (m-Mebdt)(k 1 -L)] 3 were obtained in moderate yields from the parent complexes [Fe 2 (CO) 6 (m-pdt)] and [Fe 2 (CO) 6 (m-Mebdt)] and the chelating diphosphine ligand, L = (Oxydi-2, 1-phenylene)bis(diphenylphosphine). In addition, complexes [Fe 2 (CO) 5 (m-pdt)(k 1 -LO)] 2 and [Fe 2 (CO) 5 (m-Mebdt)(k 1 -LO)] 4 containing oxidized phosphine (P = O) were obtained as side products of the reaction. In all the four complexes only one phosph… Show more

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