In this study, we investigated the dielectric properties of ovalene-like nanostructure with RKKY (Ruderman–Kittel–Kasuya–Yoshida) interactions, using Monte Carlo simulations. Nanosystem consists of an ovalene-like nanostructure with mixed spins [Formula: see text]-7/2 and S-1, separated by non-electric layers (NEL). We investigated the effect of the non-electric layers, external longitudinal electric field and ferrielectric exchange coupling on polarization and dielectric susceptibility of the nanostructure. We find that the transition temperature is affected by an increase in the number of non-electrical layers. These results can enrich the dielectric properties of ovalene-like nanostructure for future nanotechnology applications.