Dimensional ensemble and (topological) fracton thermodynamics: the slow route to equilibrium

Abstract

The use of the dimensional-ensemble becomes compulsory when spatial dimensions are not well defined. Consequently, apart from temperature, thermodynamic equilibrium requires an additional configurational parameter. Two representative cases are considered in detail: oscillators with undefined spatial dimension and topological fractons. Spatial dimension and energy are determined as a function of temperature in both cases. At low temperatures, specific heat behaves exponentially, meaning it creates a slow route to equilibrium. In accordance with experiments, calculations suggest that the spatial dimension diminishes when temperature decreases. Parameter values are computed using data obtained from almost two-dimensional graphene and porous compounds.

Prebiotic Aggregates (Tissues) Emerging from Reaction–Diffusion: Formation Time, Configuration Entropy and Optimal Spatial Dimension

“…The entropy Equation (16) has a maximum at the dimension . The quantity , analogous to in thermodynamics [ 12 , 13 , 14 , 15 ], corresponds to a parameter-defining equilibrium when the spatial dimension is fluctuating [ 52 ].…”