We present a detailed analysis of certain quantum spin systems with inhomogeneous (non-random) mean-field interactions. Examples include, but are not limited to, the interchange-and spin singlet projection interactions on complete bipartite graphs. Using two instances of the representation theoretic framework of Schur-Weyl duality, we can explicitly compute the free energy and other thermodynamic limits in the models we consider. This allows us to describe the phase-transition, the ground-state phase diagram, and the expected structure of extremal states. Contents 1. Introduction and results 1.1. Free energy 1.2. Phase transition and critical temperature 1.3. Correlations and magnetisation 1.4. Ground-state phase diagrams 1.5. Heuristics for extremal Gibbs states 1.6. Acknowledgements 2. Free energy and correlations 2.1. Interchange model: proof of Theorem 1.1 2.2. Walled Brauer algebra: proof of Theorem 1.2 2.3. Correlation functions: proof of Theorem 1.7 2.4. Magnetisation term: proof of Theorem 1.8 3. The phase-transition 3.1. Existence of a phase transition: proof of Proposition 1.3 3.2. Formulas for β c : proofs of Propositions 1.4 and 1.5 3.3. Form of the maximiser of F for c > 0 4. The ground-state phase diagram 4.1. Diagram for c > 0 4.2. Diagram for c < 0 5. Multi-block models Appendix A. The trace-inequality (75) Appendix B. Equivalence of Q i,j and P i,j in the wb-model References