Dimerization of 2-[(2-((2-aminophenyl)thio)phenyl)amino]-cyclohepta-2,4,6-trien-1-one through hydrogen bonding, C₁₉H₁₆N₂OS

Abstract

<jats:title>Abstract</jats:title><jats:p>C<jats:sub>19</jats:sub>H<jats:sub>16</jats:sub>N<jats:sub>2</jats:sub>OS, triclinic, <jats:italic>P</jats:italic>1̄ (no. 2), <jats:italic>a</jats:italic> = 8.1510(3) Å, <jats:italic>b</jats:italic> = 8.8021(3) Å, <jats:italic>c</jats:italic> = 11.3953(5) Å, <jats:italic>α</jats:italic> = 72.546(2)°, <jats:italic>β</jats:italic> = 84.568(2)°, <jats:italic>γ</jats:italic> = 80.760(2)°, <jats:italic>V</jats:italic> = 768.86(5) Å<jats:sup>3</jats:sup>, <jats:italic>Z</jats:italic> = 2, <jats:italic>R</jats:italic><jats:sub>gt</jats:sub>(<jats:italic>F</jats:italic>) = 0.0491, <jats:italic>wR</jats:italic><jats:sub>ref</jats:sub>(<jats:italic>F</jats:italic><jats:sup>2</jats:sup>) = 0.1494, <jats:italic>T</jats:italic> = 100 K.</jats:p>

Salicylaldimines: Formation via Ring Contraction and Synthesis of Mono- and Heterobimetallic Alkali Metal Heterocubanes

“…In the standard protocol for the synthesis of 2-aminotropones B , the tosyl-oxy-tropone 1 can simply be stirred in an excess of amine, if the amine is sufficiently nucleophilic, liquid at room temperature, and affordable in the required quantities (Scheme , route 1). Alternatively, stoichiometric amounts of an amine are used in the presence of a base, if the amine is valuable and/or solid at room temperature (route 2). ,,, Many primary alkylamines fulfill the requirements for the more facile route 1, isopropylamine being one of the archetypical examples. Consequently, the reaction of 1 to give 2 is one of the most common reactions in the preparation of aminotropones and aminotroponimines (Scheme a, left) .…”