1991
DOI: 10.1021/j100154a052
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Dinitrogen photoreduction to ammonia over titanium dioxide powders doped with ferric ions

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Cited by 297 publications
(159 citation statements)
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“…Furthermore, the large band gap of TiO 2 limits its application under solar light. Doping with transition metal ion into the TiO 2 matrix has been frequently reported to suppress charge carrier recombination and also for the onset shift in the band gap absorption to the visible region, thus enhancing the activity [12][13][14][15][16][17][18][19][20][21][22]. Paola et al have investigated the doping of Co, Cr, Cu, Fe, Mo, V and W into TiO 2 matrix prepared by wet impregnation method [19].…”
Section: Introductionmentioning
confidence: 99%
“…Furthermore, the large band gap of TiO 2 limits its application under solar light. Doping with transition metal ion into the TiO 2 matrix has been frequently reported to suppress charge carrier recombination and also for the onset shift in the band gap absorption to the visible region, thus enhancing the activity [12][13][14][15][16][17][18][19][20][21][22]. Paola et al have investigated the doping of Co, Cr, Cu, Fe, Mo, V and W into TiO 2 matrix prepared by wet impregnation method [19].…”
Section: Introductionmentioning
confidence: 99%
“…Due to its band-gap energy, TiO 2 utilizes only a very small fraction of the solar spectrum; thus, doping with transition metals has been employed to extend the light absorption to the visible region [1][2][3][4][5]. The presence of foreign metal species is generally detrimental for the degradation of organic species in aqueous system, but many controversial results are reported.…”
Section: Introductionmentioning
confidence: 99%
“…Various attempts have been instigated to overcome the incompetence of TiO 2 , which includes dye sensitization [10,11] and doping of transitional metal ions the TiO 2 crystal lattice etc. [12]. Although the transition metal catalysts were active in visible light, the carrier recombination occurs and low activity of the semiconductor was observed [13].…”
Section: Introductionmentioning
confidence: 99%