2019
DOI: 10.2174/1874842201906010019
|View full text |Cite
|
Sign up to set email alerts
|

Dinuclear Copper(II) 3,4,5-Tri-O-benzylgallate

Abstract: Background:Ellagitannins have attracted much attention because of the biological and pharmacological activities. In the total synthesis of ellagitannins, 3,4,5-tri-O-benzylgallic acid has been a key compound to introduce the protected galloyl group. From the perspective of coordination chemistry, 3,4,5-tri-O-benzylgallic acid is an interesting carboxylate ligand which might be capable of dinuclear carboxylate complex. Such a dinuclear carboxylate complex might be interesting as a new example of copper acetate … Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2

Citation Types

0
12
0

Year Published

2019
2019
2021
2021

Publication Types

Select...
4

Relationship

2
2

Authors

Journals

citations
Cited by 4 publications
(12 citation statements)
references
References 27 publications
0
12
0
Order By: Relevance
“…The bond distances of the Cu1 and basal O atoms are 1.9622(12) -1.9694(12)Å, which are comparable to those found in copper(II) carboxylates. 7,11,12 The apical Cu1-O11 distance is 2.1328(14)Å, which is also in the normal range as apical bonding for the copper(II) carboxylates. 7,11,12 The Cu1 atom is 0.1762(6)Å above the basal plane, defined by the four 2,4,5-trimethoxybenzoato-oxygen atoms towards the apical methanol-oxygen atom.…”
Section: Preparation and Crystal Structure Of Tetrakis(μ-245-trimethoxybenzoato-κo:κo′)bis[(methanol)copper(ii)]-nn-dimethylformamide (1/mentioning
confidence: 92%
See 4 more Smart Citations
“…The bond distances of the Cu1 and basal O atoms are 1.9622(12) -1.9694(12)Å, which are comparable to those found in copper(II) carboxylates. 7,11,12 The apical Cu1-O11 distance is 2.1328(14)Å, which is also in the normal range as apical bonding for the copper(II) carboxylates. 7,11,12 The Cu1 atom is 0.1762(6)Å above the basal plane, defined by the four 2,4,5-trimethoxybenzoato-oxygen atoms towards the apical methanol-oxygen atom.…”
Section: Preparation and Crystal Structure Of Tetrakis(μ-245-trimethoxybenzoato-κo:κo′)bis[(methanol)copper(ii)]-nn-dimethylformamide (1/mentioning
confidence: 92%
“…The Cu1-Cu1′ distance is 2.5847(5)Å, which is slightly shorter than those of 1 (2.6190(6)Å) and 2 (2.6345(12)Å). 11,12 The coordination geometry around each copper atom is an elongated square-pyramid. The bond distances of the Cu1 and basal O atoms are 1.9622(12) -1.9694(12)Å, which are comparable to those found in copper(II) carboxylates.…”
Section: Preparation and Crystal Structure Of Tetrakis(μ-245-trimethoxybenzoato-κo:κo′)bis[(methanol)copper(ii)]-nn-dimethylformamide (1/mentioning
confidence: 99%
See 3 more Smart Citations