Dinuclear Methoxy, Cyclooctadiene, and Barrelene Complexes of Rhodium(I) and Iridium(I)

Usón, Rafael; Oro, Luis A.; Cabeza, Javier A.; Bryndza, Henry E.; Stepro, M. P.

doi:10.1002/9780470132548.ch25

Cited by 331 publications

(172 citation statements)

References 15 publications

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“…65,66 Pinacolborane (HBPin) was generously supplied by BASF and was distilled before use. 2-Trimethylsilylthiophene, 67 3-trimethylsilylthiophene, 68 and 3-ptolylthiophene 69 were prepared per the literature procedures.…”

Section: General Considerationsmentioning

confidence: 99%

Iridium-catalyzed borylation of thiophenes: versatile, synthetic elaboration founded on selective C–H functionalization

et al. 2008

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Iridium-catalyzed borylation has been applied to various substituted thiophenes to synthesize polyfunctionalized thiophenes in good to excellent yields. Apart from common functionalities compatible with iridium-catalyzed borylations, additional functional group tolerance to acyl (COMe), and trimethylsilyl (TMS) groups was also observed. High regioselectivities were observed in borylation of 3-and 2,5-di-substituted thiophenes. Electrophilic aromatic C-H/C-Si bromination on thiophene boronate esters is shown to take place without breaking the C-B bond, and one-pot C-H borylation/Suzuki-Miyaura cross-coupling has been accomplished on 2-and 3-borylated thiophenes.

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Section: General Considerationsmentioning

confidence: 99%

Iridium-catalyzed borylation of thiophenes: versatile, synthetic elaboration founded on selective C–H functionalization

et al. 2008

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“…The drying agent is removed by filtration and is washed with hexane (3 x 10 mL), and the filtrate is concentrated on a rotary evaporator to give a dark brown oil. [2][3][4]4,5,3, …”

Section: Methodsmentioning

confidence: 99%

Iridium‐CatalyzedC‐HBorylation of Arenes and Heteroarenes: 1‐Chloro‐3‐iodo‐5‐(4,4,5,5‐tetramethyl‐1,3,2‐dioxaborolan‐2‐yl)benzene and 2‐(4,4,5,5,‐Tetramethyl‐1,3,2‐dioxaborolan‐2‐yl)indole

Ishiyama¹,

Takagi²,

Nobuta³

et al. 2005

Organic Syntheses

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Bis(η 4 ‐1,5‐cyclooctadiene)‐di μ‐methoxy‐diiridium(1) 4,4′‐Di‐ tert‐ butyl‐2,2′‐bipyridine Bis(pinacolato)diboron 1‐Chloro‐3‐iodobenzene Pinacolborane Indole

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“…(FMes)2BF (bis(fluoromesityl)boron fluoride), [30] (2,2'-bithiophen)-5-ylboronic acid, [31] 5-iodo-2,2'-bithiophene [32] and {Ir(μ-OMe)(COD)}2 [33] were prepared according to literature procedures. All other starting materials were purchased from commercial sources and were used without further purification.…”

Section: Experimental Section General Informationmentioning

confidence: 99%

D–π–A Triarylboron Compounds with Tunable Push–Pull Character Achieved by Modification of Both the Donor and Acceptor Moieties

Zhang

Edkins

Nitsch

et al. 2014

Chemistry A European J

130

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. (2015) 'DA triarylboron compounds with tunable pushpull character achieved by modication of both the donor and acceptor moieties.', Chemistry : a European journal., 21 (1). pp. 177-190. Further information on publisher's website: Use policyThe full-text may be used and/or reproduced, and given to third parties in any format or medium, without prior permission or charge, for personal research or study, educational, or not-for-prot purposes provided that:• a full bibliographic reference is made to the original source • a link is made to the metadata record in DRO • the full-text is not changed in any way The full-text must not be sold in any format or medium without the formal permission of the copyright holders.Please consult the full DRO policy for further details.

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Dinuclear Methoxy, Cyclooctadiene, and Barrelene Complexes of Rhodium(I) and Iridium(I)

Cited by 331 publications

References 15 publications

Iridium-catalyzed borylation of thiophenes: versatile, synthetic elaboration founded on selective C–H functionalization

Iridium-catalyzed borylation of thiophenes: versatile, synthetic elaboration founded on selective C–H functionalization

Iridium‐CatalyzedC‐HBorylation of Arenes and Heteroarenes: 1‐Chloro‐3‐iodo‐5‐(4,4,5,5‐tetramethyl‐1,3,2‐dioxaborolan‐2‐yl)benzene and 2‐(4,4,5,5,‐Tetramethyl‐1,3,2‐dioxaborolan‐2‐yl)indole

D–π–A Triarylboron Compounds with Tunable Push–Pull Character Achieved by Modification of Both the Donor and Acceptor Moieties

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