2024
DOI: 10.1002/asia.202301009
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Dipyridyl‐Fused Quinoxalineimide (DPQI): A Strong Electron‐Withdrawing Building Block for n‐Type Polymer Semiconductors

Mingwei Li,
Wanli Yang,
Rong Cheng
et al.

Abstract: Exploration of new electron‐withdrawing building blocks plays a key role in the development of n‐type organic semiconductors. Herein, a strong electron‐withdrawing building block, dipyridyl‐fused quinoxalineimide (DPQI), was successfully designed and synthesized. Single‐crystal structure reveals that DPQI molecule possesses a completely planar backbone, which is beneficial for charge transport. For comparison, dibenzo‐fused quinoxalineimide (DBQI) was also synthesized. The frontier molecular orbital (FMO) ener… Show more

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