Direct Conversion of Food Waste into 3D Porous Carbon Traps for Selective Adsorption of Cationic Dyes

Abstract

Conversion of waste biomass into valuable functional materials accomplishes the concept of circular economy in the development of sustainable waste management, and also recovery of such resources possibly reduces the requirement of feedstocks. In this scenario, the development of methodologies toward the direct conversion of the raw biomass into solid adsorbent materials without the use of any templates is highly desirable, but exceptionally challenging due to the complexity of the process. Here the direct synthesis of 3D porous carbon traps by a simple, cost‐effective, and template‐free process starting from a kitchen‐based recipe and fermented food waste is described. Precisely, a robust carbon trap is formed with a spongy structure and highly interconnected hierarchical pores after the pyrolysis of a rice‐based foam in the air. The developed materials float on water and interact efficiently with cationic dyes at static conditions. Importantly, such performance of the 3D carbon traps is not affected in the presence of anionic dyes, indicating the excellent selectivity towards the adsorption of cationic dyes. The adsorbent can be easily recovered and reused for up to 3 cycles without releasing any byproducts, thus, without causing hazardous risk of any secondary pollution to the environment.

Selective Adsorption of Methyl Orange and Methylene Blue by Porous Carbon Material Prepared From Potassium Citrate

“…After the adsorption by PC-900, the color of the mixture turned orange and only the adsorption peak at 464 nm can be observed, which indicated that MB had been almost removed from the mixture and only MO was left in the mixture. The above results intuitively indicated that when MO and MB simultaneously existed in the water, PC-900 had preferential adsorption for MB, which indicated a potential application of PC-900 in the separation of the mixed dyes. , …”

“…The above results intuitively indicated that when MO and MB simultaneously existed in the water, PC-900 had preferential adsorption for MB, which indicated a potential application of PC-900 in the separation of the mixed dyes. 37,54 3.3.5. Regeneration Performance Study.…”