“…Compared to the conventional TOF-ICR technique, the PI-ICR method offers a gain in precision and resolving power of approximately 5 and 50, respectively. This has made it feasible to carry out measurements of mass ratios of long-lived nuclides with an uncertainty of just a few tens of eV at on-line Penning-trap facilities (Nesterenko et al, 2014;Eliseev et al, 2015;Karthein et al, 2019 (Block et al, 2007) and three pairs have been investigated with the mass spectrometers JYFLTRAP (Kolhinen et al, 2004) and TRIGATRAP (Ketelaer et al, 2008) and the Florida State University Penning trap (Shi, Redshaw, and Myers, 2005), which are in many aspects similar to SHIPTRAP, the experiments on the determination of the Q values are described here by the example of the SHIPTRAP mass spectrometer.…”