Tungsten oxides are a family of transition metal oxides with fascinating physical and chemical properties that make them suitable for application in many research fields, including photocatalysis and photoelectrochemistry, [1-3] gas and pH sensing, [4-6] or energy storage. [7] W oxides can form in a wide range of crystalline structures and compositions, [8] including substoichiometric compounds, conventionally denoted as WO 3-x (0 < x < 0.4). Such suboxides are characterized by crystallographic defects, namely, oxygen vacancies ("planar defects"), which provide unique properties.