1981
DOI: 10.1016/0166-6622(81)80058-3
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Direct measurement of the effect of meniscus forces on adhesion: A study of the applicability of macroscopic thermodynamics to microscopic liquid interfaces

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Cited by 192 publications
(112 citation statements)
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“…A reduced value of the water surface tension as low as γ lv ∼ 40 mN/m could indeed provide the adequate extrusion pressures. However, such a large deviation from the macroscopic value is consistent with neither the 1/R p scaling of the intrusion pressure found in the MCM-41 nor the state-of-the-art numerical models (32,33) or capillary forces investigations (34,35). Actually, the smallest radius of curvature of water menisci reached in our experiments, obtained for MCM-41 intrusion, is of 3.2 nm, not really a molecular value.…”
Section: Discussionsupporting
confidence: 68%
“…A reduced value of the water surface tension as low as γ lv ∼ 40 mN/m could indeed provide the adequate extrusion pressures. However, such a large deviation from the macroscopic value is consistent with neither the 1/R p scaling of the intrusion pressure found in the MCM-41 nor the state-of-the-art numerical models (32,33) or capillary forces investigations (34,35). Actually, the smallest radius of curvature of water menisci reached in our experiments, obtained for MCM-41 intrusion, is of 3.2 nm, not really a molecular value.…”
Section: Discussionsupporting
confidence: 68%
“…This is with AFM [69,119,[190][191][192][193][194][195][196][197][198]. Many experiments showed a significant dependency of the adhesion force on the relative humidity [40,52,54,56,57,183]. A continuous increase humidity was, for example, observed for the interaction of a silicon nitride tip with mica [194], between silica particles [199], a silica particle and a silicon wafer [200], or between a silicon nitride tip and molybdenum trioxide [201].…”
Section: Influence Of Humidity On Adhesionmentioning
confidence: 99%
“…The reduced Laplace pressure in the meniscus and the surface tension of the liquid cause an attractive force [53]. Many experiments showed a significant dependency of the adhesion force on the vapor pressure [52,[54][55][56][57].…”
Section: Introductionmentioning
confidence: 99%
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“…Further evidence relating to the fundamental nature of capillary menisci was gathered by Fisher and Israelachvili [14] and Christenson [15] using the surface force apparatus. This instrument and its applications to force measurement have been reviewed by Luckham [16].…”
Section: A Historical Perspective Of Experimental Studiesmentioning
confidence: 99%