This work presents high spectral resolution observations of the [C ii] line at 158 μm, one of the major cooling lines of the interstellar medium, taken with the HIFI heterodyne spectrometer on the Herschel satellite. In BCLMP 691, an H ii region far north (3. line to far-infrared continuum ratio suggests a photoelectric heating efficiency of 1.1%. The data, together with published models indicate a UV field G 0 ∼ 100 in units of the solar neighborhood value, a gas density n H ∼ 1000 cm −3 , and a gas temperature T ∼ 200 K. Adopting these values, we estimate the C + column density to be N C + ≈ 1.3 × 10 17 cm −2 . The [C ii] emission comes predominantly from the warm neutral region between the H ii region and the cool molecular cloud behind it. From published abundances, the inferred C + column corresponds to a hydrogen column density of N H ∼ 2 × 10 21 cm −2 . The CO observations suggest that N H = 2N H 2 ∼ 3.2 × 10 21 cm −2 and 21 cm measurements, also at 12 resolution, yield N H i ≈ 1.2 × 10 21 cm −2 within the [C ii] velocity range. Thus, some H 2 not detected in CO must be present, in agreement with earlier findings based on the SPIRE 250−500 μm emission.