Direct Observation of HONO Emissions from Real-World Residential Natural Gas Heating in China

Abstract

Atmospheric nitrous acid (HONO) is an important precursor of atmospheric hydroxyl radicals. Vehicle emissions and heterogeneous reactions have been identified as major sources of urban HONO. Here, we report on HONO emissions from residential natural gas (RNG) for water and space heating in urban areas based on in situ measurements. The observed HONO emission factors (EFs) of RNG heating vary between 6.03 and 608 mg·m–3 NG, which are highly dependent on the thermal load. The highest HONO EFs are observed at a high thermal load via the thermal NO homogeneous reaction. The average HONO EFs of RNG water heating in winter are 1.8 times higher than that in summer due to the increased thermal load caused by the lower inlet water temperatures in winter. The power-based HONO EFs of the traditional RNG heaters are 1085 times and 1.7 times higher than those of gasoline and diesel vehicles that meet the latest emission standards, respectively. It is estimated that the HONO emissions from RNG heaters in a typical Chinese city are gradually close to emissions from on-road vehicles when temperatures decline. These findings highlight that RNG heating is a non-negligible source of urban HONO emissions in China. With the continuous acceleration of coal-to-gas projects and the continuous tightening of NOx emission standards for vehicle exhaust, HONO emissions from RNG heaters will become more prominent in urban areas. Hence, it is urgently needed to upgrade traditional RNG heaters with efficient emission reduction technologies such as frequency-converted blowers, secondary condensers, and low-NOx combustors.

Unveiling the underestimated direct emissions of nitrous acid (HONO)

“…For BB, δ 15 N-NO x was −1.4 ± 4.2‰ and δ 15 N bulk -N 2 O was +3.5 ± 2.0‰, while for CC, δ 15 N-NO x was +11.4 ± 3.1‰ and δ 15 N bulk -N 2 O was +8.3 ± 4.8‰. HONO has been suggested as an intermediate product in the conversion of NO to NO 2 ( 78 , 79 ). The overlapping N isotopes of NO x and HONO from the combustion-related processes indicate minor isotopic fractionation in this series of reactions.…”