2023
DOI: 10.1002/ange.202305881
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Direct Observation of the Ethyl Radical in the Pyrolysis of Ethane

Nadav Genossar‐Dan,
Sharona Atlas,
Dana Fux
et al.

Abstract: We report the first direct detection of ethyl radical in the pyrolysis of ethane. Observation of this vital intermediate was made possible in this extremely reactive environment by the use of a microreactor coupled with synchrotron radiation and photoelectron photoion coincidence (PEPICO) spectroscopy, despite its short lifetime and low concentration. Together with ab‐initio master equation‐calculated rates and fully coupled computational fluid dynamics simulations, our measurements show that even under the lo… Show more

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