This review, as did the previous three reviews in this series, attempts to cover a cross section of the methods for the determination of zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, and tungsten. Procedures using all of the more common techniques are mentioned along Element Zirconium Vanadium Niobium Chromium Tungsten Table V. Electrometric Methods Method: Reagent: Material (References)Amperometric: EDTA: Th, Fe, In, Cu, Zn, Pb, Ni, Mg (304); Ni (702) Polarographic: study of conditions (414) Amperometric: Fe(II): study of accuracy (511); Fe, Cr (602); V salts (603)