2014
DOI: 10.1038/ncomms4342
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Direct synthesis of single-walled aminoaluminosilicate nanotubes with enhanced molecular adsorption selectivity

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Cited by 78 publications
(97 citation statements)
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References 44 publications
(93 reference statements)
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“…Confinement of reactants and intermediates inside nanoporous PCs has also started to be explored and observed to benefit reaction selectivity 3. To foster optimized integration of these currently disconnected research strategies into chemically selective alternatives to photoferroelectrics for polarization‐enhanced photocatalysis, here we investigate an emerging class of cheap 1D nanomaterials, namely, hybrid inorganic–organic imogolite nanotubes (Imo‐NTs) 6. Linear‐scaling density functional theory (DFT) simulations elucidate the interplay between NT functionalization, curvature, permanent polarization, band gap (BG), band‐separation, band‐alignment, and charge‐transfer excitations, enabling informed design of a novel class of locally polarized, selective porous PCs.…”
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confidence: 99%
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“…Confinement of reactants and intermediates inside nanoporous PCs has also started to be explored and observed to benefit reaction selectivity 3. To foster optimized integration of these currently disconnected research strategies into chemically selective alternatives to photoferroelectrics for polarization‐enhanced photocatalysis, here we investigate an emerging class of cheap 1D nanomaterials, namely, hybrid inorganic–organic imogolite nanotubes (Imo‐NTs) 6. Linear‐scaling density functional theory (DFT) simulations elucidate the interplay between NT functionalization, curvature, permanent polarization, band gap (BG), band‐separation, band‐alignment, and charge‐transfer excitations, enabling informed design of a novel class of locally polarized, selective porous PCs.…”
mentioning
confidence: 99%
“…Progress has also been made in the post‐synthetic selective functionalization of the outer or inner surface of AlSi NTs,10 and in the synthesis of hybrid organic–inorganic methylated (AlSi‐Me) or aminated AlSi NTs derivatives, that have —CH 3 ( Figure 1 a) and —CH 2 —NH 2 groups in the NT cavity 6. Synthesis of hybrid methylated Al(Si/Ge)‐Me NTs with a tunable Si/Ge ratio has also been reported.…”
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confidence: 99%
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