2024
DOI: 10.1039/d3sc05977d
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Direct synthesis of spirobifluorenes by formal dehydrative coupling of biaryls and fluorenones

Yugo Kato,
Kazutoshi Nishimura,
Yuji Nishii
et al.

Abstract: A Tf2O-mediated, direct dehydrative coupling of (hetero)biaryls and fluorenones proceeds to form the corresponding spirobifluorenes in good to high yields. The reaction system allows the relatively simple nonhalogenated and nonmetalated...

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