Directing Group Assisted
            <i>meta</i>
            ‐
            <scp>C</scp>
            –
            <scp>H</scp>
            Functionalization of Arenes Aided by Norbornene as Transient Mediator

Cheng, Hong‐Gang; Zhou, Qianghui

doi:10.1002/9783527824137.ch4

Remote CH Bond Functionalizations 2021

DOI: 10.1002/9783527824137.ch4

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Directing Group Assisted meta ‐ C – H Functionalization of Arenes Aided by Norbornene as Transient Mediator

Hong‐Gang Cheng

Qianghui Zhou

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2022

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Palladium/Norbornene Cooperative CatalyticCHFunctionalization

Knight

Ferreira

2022

Handbook of CH-Functionalization

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Palladium‐catalyzed cross‐coupling and CH functionalization methods have long‐established selectivity and reactivity rules. Typically, these transformations afford a single new bond at a precise location on the substrate. Through the advancement of CH functionalization chemistry in the area of cooperative palladium/norbornene catalysis, novel selectivities and reactivities are possible. This cooperativity provides the opportunity to generate new bonds at remote or unreactive positions and afford multisubstituted products from simpler monofunctionalized starting materials. A robust understanding of these mechanistic steps is critical to understanding these reactions and utilizing their potential. Herein, we describe the mechanistic features and transformations of palladium/norbornene cooperative catalytic CH functionalizations.

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Palladium/Norbornene Cooperative CatalyticCHFunctionalization

Knight

Ferreira

2022

Handbook of CH-Functionalization

View full text Add to dashboard Cite

show abstract

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Directing Group Assisted meta ‐ C – H Functionalization of Arenes Aided by Norbornene as Transient Mediator

Cited by 1 publication

References 69 publications

Palladium/Norbornene Cooperative CatalyticCHFunctionalization

Palladium/Norbornene Cooperative CatalyticCHFunctionalization

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