Directional Bias in Molecular Photogearing Evidenced by LED‐Coupled Chiral Cryo‐HPLC
Frederik Gnannt,
Aaron Gerwien,
Sven Waldmannstetter
et al.
Abstract:Molecular gearing systems are technomimetic nanoscale analogues to complex geared machinery in the macroscopic world and are likewise defined as systems incorporating intermeshed elements which perform correlated rotational motions by mechanical engagement. Only recently, new methods to actively drive molecular gearing motions instead of relying on passive thermal activation have been developed. Further progress in this endeavor will pave the way for unidirectional molecular gearing devices with a distinct typ… Show more
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