Direkter Nachweis von Dicyanthioketen in der Gasphase

Abstract

Dicyanthioketen (2), das erste Thioketen überhaupt, konnte bei 470°C/0.05 mbar aus (1) erzeugt und durch temperaturabhängige PE‐Spektroskopie (VTPES) charakterisiert werden.

Thermal transformations of organic compounds of divalent sulfur

“…However, this thioketene appeared to be extremely unstable and was characterised only by PES. 158 Dithiaspirocycloalkanes with five-and six-membered rings undergo pyrolysis at 600 8C to give cyclopentanethione or cyclohexanethione. 159 Ethylenedithioketal of quadricyclanone undergoes extensive fragmentation at 200 8C to form benzene and hydrogen sulfide.…”