Discernment of synergism in pyrolysis of biomass blends using thermogravimetric analysis

Mallick, Debarshi; Poddar, Maneesh Kumar; Mahanta, Pinakeswar; Moholkar, Vijayanand S.

doi:10.1016/j.biortech.2018.04.011

Cited by 193 publications

(94 citation statements)

References 46 publications

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“…However, the residues obtained from the pyrolysis of blends were much lower than the SWD pyrolysis residue. This could be because of evolution of hot gaseous species as a result of thermal decomposition of volatile matter or could be because of thermal decomposition of biomass enhanced by catalytic activity of metal contents in the MA and SWD ash [33].…”

Section: Resultsmentioning

confidence: 99%

“…This is equivalent to a complete lack of synergistic interaction between the two biomass samples during pyrolysis, so that the calculated values are the sum of individual values proportional to their mass ratio. More detailed explanation regarding the procedure can be obtained from the work done by Mallick et al [33], The weighted residual mass values as functions of time can be obtained from the following equation:where f MA is the fraction of microalgae in the mixture, and α MA and α SWD are the conversions of individual biomasses at a given time. Hence, if individual biomasses are pyrolysed independently, α cal can be defined as theoretical conversion of a given biomass blend with zero synergy.…”

Section: Resultsmentioning

confidence: 99%

“…The plausible reason could be that the extractives present in MA biomass may not have enhanced the degradation of structural components in SWD biomass, majorly lignin, cellulose, and hemicellulose. Furthermore, the synergistic effect of additional heating due to volatiles content is also limited as the SWD biomass contain lower volatiles when compared with other forms of biomass such as lignocellulosic biomass [33]. As a result, the activation energy of blends is marginally higher than that of MA biomass.…”

Section: Resultsmentioning

confidence: 99%

See 2 more Smart Citations

Thermogravimetric and kinetic analysis to discern synergy during the co-pyrolysis of microalgae and swine manure digestate

Vuppaladadiyam

Hao²,

Zhao

et al. 2019

Biotechnol Biofuels

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Background Co-pyrolysis of wastes with other feedstock can synergistically improve the rate of biomass decomposition and also help to resolve the issues related to limited availability feedstock. In this regards, synergistic interaction between feedstock during co-pyrolysis is an important aspect of research. As the constituents of aquatic and lignocellulosic biomass are different, and the decomposition pattern of aquatic biomass is dissimilar when compared to lignocellulosic biomass, it is important to understand whether these two biomasses interact during co-pyrolysis. Results Synergism in the co-pyrolysis of microalgae (MA), swine manure digestate (SWD), and their blends (MA/SWD) (w/w %), 2.5/7.5 (MD-1), 5/5 (MD-2), and 7.5/2.5 (MD-3), was evaluated based on decomposition behavior, gas yields, extent of thermal degradation, and kinetics. Extractives and volatiles in biomass enhanced the reaction kinetics and products yields, as indicated by the reduction in apparent activation energy of the blends, accompanied by an increase in H 2 , total gas yield, and extent in degradation. Thermogravimetric data, via isoconversional methods, were interpreted to achieve the apparent activation energies for the thermal degradation of the MA, SWD, and their blends. The best fit reaction models were identified using compensation effect and generalized master plots methods. Semi-quantitative method was used to quantify the evolved gas species. H 2 , CO, and CO 2 were noted to be the dominant gases, implying that tar cracking and reforming reactions were predominant. Conclusions Overall, synergy was noticed with respect to the pyrolysis of SWD biomass to gas products in the presence of MA biomass, whereas synergy was witnessed up to 50 w/w % MA in view of kinetic parameters as evaluation criteria.

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Section: Resultsmentioning

confidence: 99%

Section: Resultsmentioning

confidence: 99%

Section: Resultsmentioning

confidence: 99%

See 1 more Smart Citation

Thermogravimetric and kinetic analysis to discern synergy during the co-pyrolysis of microalgae and swine manure digestate

Vuppaladadiyam

Hao²,

Zhao

et al. 2019

Biotechnol Biofuels

View full text Add to dashboard Cite

show abstract

“…The test was performed on a PerkinElmer STA 6000 (See Table 2) using a nitrogen flow of 20 mL/min for inert atmosphere and a temperature growth rate of 20 • C/min. The content of each type of matter was determined from the thermogravimetric profile (variation of sample mass versus temperature), taking into account the inflection points of the mass derivative as a function of time [41,42]. The calorific value was determined using a digital bomb calorimeter (model: IKA C 2000) [43] in which small samples were subjected to complete combustion in an adiabatic environment (Table 3).…”

Section: Ultimate Analysismentioning

confidence: 99%

Co-Combustion of Waste Tires and Plastic-Rubber Wastes with Biomass Technical and Environmental Analysis

et al. 2020

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The present work studies the possibility of energy recovery by thermal conversion of combustible residual materials, namely tires and rubber-plastic, plastic waste from outdoor luminaires. The waste has great potential for energy recovery (HHV: 38.6 MJ/kg for tires and 31.6 MJ/kg for plastic). Considering the thermal conversion difficulties of these residues, four co-combustion tests with mixtures of tires/plastics + pelletized Miscanthus, and an additional test with 100% Miscanthus were performed. The temperature was increased to the maximum allowed by the equipment, about 500 °C. The water temperature at the boiler outlet and the water flow were controlled (60 °C and 11 L/min). Different mixtures of residues (0–60% tires/plastics) were tested and compared in terms of power and gaseous emissions. Results indicate that energy production increased with the increase of tire residue in the mixture, reaching a maximum of 157 kW for 40% of miscanthus and 60% of tires. However, the automatic feeding difficulties of the boiler also increased, requiring constant operator intervention. As for plastic and rubber waste, fuel consumption generally decreased with increasing percentages of these materials in the blend, with temperatures ranging from 383 °C to 411 °C. Power also decreased by including such wastes (66–100 kW) due to feeding difficulties and cinder-fusing problems related to ash melting. From the study, it can be concluded that co-combustion is a suitable technology for the recovery of waste tires, but operational problems arise with high levels of residues in the mixture. Increasing pollutant emissions and the need for pre-treatments are other limiting factors. In this sense, the thermal gasification process was tested with the same residues and the same percentages of mixtures used in the co-combustion tests. The gasification tests were performed in a downdraft reactor at temperatures above 800 °C. Each test started with 100% acacia chip for reference (like the previous miscanthus), and then with mixtures of 0–60% of tires and blends of plastics and rubbers. Results obtained for the two residues demonstrated the viability of the technology, however, with mixtures higher than 40% it was very difficult to develop a process under stable conditions. The optimum condition for producing a synthesis gas with a substantial heating value occurred with mixtures of 20% of polymeric wastes, which resulted in gases with a calorific value of 3.64 MJ/Nm3 for tires and 3.09 MJ/Nm3 for plastics and rubbers.

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“…38 Considering isoconversional models, the limitation of E a estimative regarding high values of conversion is commonly mentioned in literature. 27,[38][39][40][41][42] The fit quality is commonly evaluated by R 2 and values higher than 0.95 were considered for trustful estimation of E a , as commented by previous works. 17,19 The isoconversional models of KAS and Friedman showed the dependence between E a values and mass conversion, what was also observed previously.…”

Section: Single Reaction Step Modelsmentioning

confidence: 99%

Kinetic Parameters Study for the Slow Pyrolysis of Coffee Residues Based on Thermogravimetric Analysis

et al. 2020

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Thermal decomposition of coffee husks was investigated by thermogravimetric analyses. The proximate, ultimate and composition analyses were performed. Thermogravimetric tests were realized, the material was heated to 1173 K using five heating rates: 5, 10, 15, 20, 25 K min -1 . The kinetic parameters were estimated using the methods of Kissinger-Akahira-Sunose and Friedman, the distributed activation energy model and the independent parallel reactions model. The isoconversional models of Kissinger-Akahira-Sunose and Friedman showed the dependence between determined values of activation energy and mass conversion, the activation energy values varied from 1437.39 to 199.22 kJ mol -1 for Kissinger-Akahira-Sunose and from 127.81 to 230.35 kJ mol -1 for Friedman model. The values of activation energy were determined for Miura-Maki method; varying from 137.39 to 199.22 kJ mol -1 . The model of parallel and independent reactions showed the presence of six different reactions (with activation energy values varying from 42.0 to 214.2 kJ mol -1 ) occurring during coffee husks pyrolysis, indicating a complex reaction. Currently, works regarding the determination of kinetic parameters for coffee husks pyrolysis are not common. The present work is the first report using the model of parallel and independent reactions to estimate kinetic parameters for pyrolysis of coffee husks, a residue widely generated worldwide.

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Discernment of synergism in pyrolysis of biomass blends using thermogravimetric analysis

Cited by 193 publications

References 46 publications

Thermogravimetric and kinetic analysis to discern synergy during the co-pyrolysis of microalgae and swine manure digestate

Thermogravimetric and kinetic analysis to discern synergy during the co-pyrolysis of microalgae and swine manure digestate

Co-Combustion of Waste Tires and Plastic-Rubber Wastes with Biomass Technical and Environmental Analysis

Kinetic Parameters Study for the Slow Pyrolysis of Coffee Residues Based on Thermogravimetric Analysis

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