We present our spectroscopic observations of V455 Andromedae during the 2007 superoutburst. Our observations cover this superoutburst from around the optical peak of the outburst to the post-superoutburst stage. During the early superhump phase, the emission lines of Balmer series, He I, He II, Bowen blend, and C IV / N IV blend were detected. He II 4686 line exhibited a double-peaked emission profile, where Balmer emission lines were single-peaked, which is unexpected from its high inclination. In the ordinary superhump phase, Balmer series