Abstract. Berlinite single crystal specimens were shocked to peak pressures 12 and 24 GPa. Specimens were placed in an AI capsule to minimize shock-wave reflections at interfaces between specimen and capsule. Shock pressures were achieved with a 6.5-m-long two-stage gun. The shock-induced microstructures in recovered specimens were then investigated by Transmission Electron Microscopy. In the sample shocked at 12 GPa, the prominent shock-induced defects are dislocations and basal a glide appears to be the only glide system activated. In contrast, the sample shocked at 24 GPa exhibits no dislocations. The material is partially converted into an amorphous phase occurring under the form of thin amorphous lamellae parallel to the {10in} planes (n=0, 2, 3, 4). This microstructure is very similar to the one observed in experimentally shocked quartz.