Snow precipitation and snowpack are commonly used to assess the condition of the aerial environment. Another way to monitor air quality is to study trees and shrubs, which are natural barriers for capturing air pollution, including atmospheric particulate matter. The hypothesis of the current study was that using fresh snow precipitation and washout from vegetation for the monitoring of air pollution can produce comparable results. In this study, we compared the results of laser diffraction analysis of suspended particular matter in melted fresh snow and ultrasound-treated washout from conifer needles. The samples were collected at several sites in Primorsky Krai, Russian Federation, and analyzed according to the same scheme. We observed that the content of particulate matter with a smaller aerodynamic diameter in the ultrasound-treated washout from conifer needles was higher than that in the melted fresh snow. The content of PM10 in the ultrasound-treated washout from conifers was increased by 6–27% depending on the site, showing greater efficacy of this method. This method can be used as an alternative to the sampling of snow for the monitoring of ambient air pollution, taking into account several limitations.