Quaternized polymers are critical components for various
energy
devices. Vinyl-addition polynorbornenes provide high mechanical strength,
high ion conductivity, and chemical stability in a wide range of pH
environments due to the all-C–C bond backbone. Herein, we present
the synthesis of a series of quaternized polynorbornene random copolymers
via vinyl addition polymerization and elucidate the impact of polymer
composition on their properties. The quaternary ammonium alkyl tether
length and the ratio of n-hexylnorbornene to unsubstituted
norbornene are systemically tailored. A copolymer of 5-(3-bromopropyl)-2-norbornene
and norbornene with pendant trimethylammonium groups achieved hydroxide
conductivity of 109 mS/cm at 80 °C with a modest water uptake
of 72%. The addition of n-hexylnorbornene to the
copolymer, to make a terpolymer, allows for the polymer composition
to be tailored for properties, including a decrease in water uptake
and higher processability, despite a slightly decreased hydroxide
conductivity. Moreover, the developed membranes are chemically robust
and highly mechanically stable, enabling thin membranes to be easily
fabricated. This study provides insight into important design parameters
for quaternized polynorbornenes for a variety of energy storage and
conversion devices, especially fuel cells.