Using a Vlasov-Poisson model, a numerical investigation of the dispersion relation for ion Bernstein waves in a kappa-distributed plasma has been carried out. The dispersion relation is found to depend significantly on the spectral index of the ions, κi, the parameter whose smallness is a measure of the departure from thermal equilibrium of the distribution function. Over all cyclotron harmonics, the typical Bernstein wave curves are shifted to higher wavenumbers (k) if κi is reduced. For waves whose frequency lies above the lower hybrid frequency, ωLH, an increasing excess of superthermal particles (decreasing κi) reduces the frequency, ωpeak, of the characteristic peak at which the group velocity vanishes, while the associated kpeak is increased. As the ratio of ion plasma to cyclotron frequency (ωpi/ωci) is increased, the fall-off of ω at large k is smaller for lower κi and curves are shifted towards larger wavenumbers. In the lower hybrid frequency band and harmonic bands above it, the frequency in a low-κi plasma spans only a part of the intraharmonic space, unlike the Maxwellian case, thus exhibiting considerably less coupling between adjacent bands for low κi. It is suggested that the presence of the ensuing stopbands may be a useful diagnostic for the velocity distribution characteristics. The model is applied to the Earth's plasma sheet boundary layer in which waves propagating perpendicularly to the ambient magnetic field at frequencies between harmonics of the ion cyclotron frequency are frequently observed.