Abstract. We study solute transport in porous media with periodic microstructures consisting of interconnected thin channels. We discuss a local physical mechanism that occurs at the intersections of channels and promotes mixing of the solute with the solvent (i.e., the host liquid). We identify the parameter regime, where this mechanism is the dominant cause of dispersion, and obtain the effective or macroscopic transport equation that the concentration of solute satisfies when the medium is subjected to a time periodic applied pressure gradient. We conclude with illustrative examples. 1. Introduction. A porous medium is a material that contains relatively small spaces filled with fluid (such as a gas, a liquid, or a mixture of different fluids) embedded in a solid matrix. These fluid filled spaces are called pores or voids. With the exception of metals, some dense rocks, and some plastics, virtually all solid materials are porous to varying degrees.Solutes are materials that dissolve in liquids forming solutions. An example is salt (not at very large concentrations) in water. The host liquid, such as water in the mentioned example, is called the solvent. The transport of a solute in porous media depends on several factors, including the solvent and solute properties, the fluid velocity field within the porous medium, and the microgeometry, i.e., shape, size, and location of the solid part of the medium and the voids. The objective of this paper is to provide new tools for the study of the influence of these factors on solute transport.Solute transport in liquid filled porous media plays a significant role in several phenomena of scientific and technological importance including the transport of contaminants in soils [17,32], the transport of nutrients in bones [50,45,43,44,65,39], the intrusion of salt in fresh water in soils near ocean coasts, movement of minerals (e.g., fertilizers) in soils, secondary recovery techniques in oil reservoirs (where the injected fluid dissolves the reservoir's oil), the use of tracers in petroleum engineering and hydrology research projects, etc. (see more about these and other examples in [14,6,9,19,30,58]).Several theoretical methods are used to study solute transport in porous media [23]. These include the use of numerical experiments on networks of channels with varying widths forming regular grids [2,15,16,20,27,58,59], percolation methods [2,7,8,10,47,55,56,57,59,62], numerical experiments on media with fractal geometry [2,16,59,64], assuming periodic media and calculating the effective transport equation by means of the method of moments [2,11,12,13,14,31]