Based upon a one-dimensional nonlinear Klein-Gordon equation with a perturbed one-gap periodic potential, this paper deals with the question as to whether spatially localized structures in periodic media can exist for all times. As it turns out that, given our model equation, the latter question cannot be answered in the affirmative, we show the asymptotic stability of the vacuum state in appropriate dispersive norms and provide an upper bound for the temporal decay rates of the corresponding solutions. This is done by using the dispersive estimates proved in [23]. More precisely, if the perturbed Hill operator associated to our problem has no eigenvalue, we add a power nonlinearity u p with p ∈ {6, 7, 8, . . .}. In this setting, the convergence to the trivial solution w. r. t. the L ∞ norm is shown in a canonical way. We obtain the corresponding linear rate. In contrast, if the spatially localized potential creates an eigenvalue in the band gap of the continuous spectrum, then we multiply u p by a spatial weight function and prove an asymptotic stability result w. r. t. a weighted L 2 norm for p ∈ {3, 4, 5, . . .}. Now, in the presence of an eigenvalue, there is a strongly reduced decay compared to the associated linearized problem. It is due to the component that belongs to the discrete spectral subspace of L 2 w. r. t. the perturbed Hill operator. As in [29], this phenomenon is referred to as metastability of the corresponding solutions.