Observations of pore structure in thin-sections are related to the performance of stable, first-contact-miscible displacements in reservoir cores and then to simulations of displacement performance of CO 2 corefloods. Results of effluent composition measurements are reported for miscible displacements in seven core samples-three sandstones and four San Andres carbonates from west Texas or eastern New Mexico. Those displacements are interpreted by fitting the measured effluent compositions to the Coats-Smith (C-S) model, which represents the flow as occurring in flowing and stagnant fractions with mass transfer between them. Observations of thin-sections, including measurements of pore-size distributions and a simple measurement of spatial correlation of pore sizes, are also reported. Comparison of displacement results and thin-section data indicates that wide pore-size distributions and preferential flow paths are characterized in the C-S model by high dispersion coefficients and low flowing fractions. Simulations of the interactions of phase behavior and flow in nonuniform pore structures indicate that wide poresize distributions and preferential flow paths can significantly increase residual oil saturations (ROS's) in CO 2 floods over those for uniform pore structures. Thus, heterogeneities observable at the scale of a thin-section have significant effects in laboratory core but much smaller effects in displacements at field scale. Large-scale heterogeneities present in field floods, however, probably cause similar increases in residual saturation in some fields.