2024
DOI: 10.1002/ange.202313067
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Disproportionation of Co2+ in the Topochemically Reduced Oxide LaSrCoRuO5

Zhilin Liang,
Maria Batuk,
Fabio Orlandi
et al.

Abstract: Complex transition‐metal oxides exhibit a wide variety of chemical and physical properties which are a strong function the local electronic states of the transition‐metal centres, as determined by a combination of metal oxidation state and local coordination environment. Topochemical reduction of the double perovskite oxide, LaSrCoRuO6, using Zr, yields LaSrCoRuO5. This reduced phase contains an ordered array of apex‐linked square‐based pyramidal Ru3+O5, square‐planar Co1+O4 and octahedral Co3+O6 units, consis… Show more

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