“…The formation of intermetallic compounds at the aluminum–titanium interface is also of great concern [ 1 , 2 , 3 ]. Usually, intermetallic TiAl 3 has been reported to form [ 2 , 3 , 5 , 6 , 7 , 8 , 9 , 10 , 11 , 12 , 13 , 14 , 15 , 16 , 17 , 18 , 19 ], presumably due to the comparatively low free energy of the intermetallic reaction in this case [ 20 ]. However, the details of this process are unclear.…”