Dissipation and Residue Pattern of Dinotefuran, Fluazinam, Indoxacarb, and Thiacloprid in Fresh and Processed Persimmon Using LC-MS/MS

Noh, Hyun-Ho; Jo, Seung-Hyeon; Shin, Hyeon-Woo; Kim, Dong-Ju; Ham, Young-Jin; Kim, Junyoung; Kim, Dan-Bi; Kwon, Hye-Young; Kyung, Kee-Sung

doi:10.3390/foods11030416

Cited by 4 publications

(1 citation statement)

References 33 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Pesticides are indispensable agricultural materials that can protect crops from various pests, including insects, nematodes, mites, rodents, fungi, and weeds; these ensure high-quality agricultural products and stable income for the farmers [ 1 , 2 , 3 , 4 ]. These pesticides remain on crops through spraying or have a long half-life.…”

Section: Introductionmentioning

confidence: 99%

Development of Simultaneous Analytical Method for Imidazolinone Herbicides from Livestock Products by UHPLC-MSMS

Heo

Chang

et al. 2022

Foods

View full text Add to dashboard Cite

A simultaneous analytical method, which used LC/MSMS for imidazolinone herbicides from livestock products (egg, milk, beef, pork, and chicken) for monitoring, was developed with a QuEChERS preparation. A weighed sample (5 g) in a 50 mL conical tube was added to 0.1 M potassium phosphate dibasic solution (5 mL) and shaken for 10 min. After shaking, 0.5 mL of 6 N HCl and 5 mL of acetonitrile were added, and this solution was shaken for 10 min. Additionally, QuEChERS extraction salts (original method, 4 g MgSO4, 1 g NaCl) were added to the sample in a 50 mL conical tube. The mixture was strongly shaken for 1 min and centrifuged at 3000× g for 10 min. The acetonitrile layer was purified with dSPE (150 mg MgSO4, 25 mg C18) and was centrifuged at 13,000× g for 5 min. The supernatant was filtered with a membrane filter (pore size: 0.2 μm) before analysis. The ME (%, matrix effect) range for almost all analytes was −6.56 to 7.11%. MLOD (method limit of detection) and MLOQ (method limit of quantitative) values were calculated by the S/N ratio. MLOQs were 0.01 mg/kg. The linear correlation coefficients (R2) were >0.99 with the range of 0.5~25 μg/kg for all of the imidazolinone herbicides. The recoveries (of imidazolinone herbicides) were in the range of 76.1~110.6% (0.01 mg/kg level), 89.2~97.1% (0.1 mg/kg level), and 94.4~104.4% (0.5 mg/kg level). These are within the validation criteria (to recover 70–120% with RSD <20%). The method demonstrated the simple, rapid, high throughput screening and quantitative analysis of imidazolinone herbicide residues for monitoring in livestock products.

show abstract

Section: Introductionmentioning

confidence: 99%