1983
DOI: 10.1111/j.1365-2621.1983.tb00317.x
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Dissociation constant of sorbic acid in water and water‐glycerol mixtures at 25°C from conductance measurements

Abstract: Molar conductivities of dilute solutions of sorbic acid in water, and in the mixed solvents water +lo, 20,30,40 and 50% glycerol by mass at 25°C are reported. The results have been analysed with the Pitts conductance equation and pK, values for sorbic acid in these solvent mixtures are tabulated. Similar data for sorbic acid in water+30% glycerol at 10°C are also included. The implications of the results for the role of sorbic acid in food preservation are discussed.

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Cited by 21 publications
(5 citation statements)
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“…The results in the present study confirmed the dependence of preservative upon the pH as reported earlier by several studies (Sofos and Busta, 1981;Earle and Putt, 1984;Praphailong and Fleet, 1997;Fustier et al, 1998;Stratford and Anslow, 1998). Weak acid preservative, potassium sorbate is more effective towards inhibiting microorganisms in their undissociated forms, which increase in concentration as the pH decreases (Pethybridge et al, 1983;Eklund, 1983Eklund, , 1985Gould, 1996;Davidson, 1997).…”
Section: Resultssupporting
confidence: 80%
“…The results in the present study confirmed the dependence of preservative upon the pH as reported earlier by several studies (Sofos and Busta, 1981;Earle and Putt, 1984;Praphailong and Fleet, 1997;Fustier et al, 1998;Stratford and Anslow, 1998). Weak acid preservative, potassium sorbate is more effective towards inhibiting microorganisms in their undissociated forms, which increase in concentration as the pH decreases (Pethybridge et al, 1983;Eklund, 1983Eklund, , 1985Gould, 1996;Davidson, 1997).…”
Section: Resultssupporting
confidence: 80%
“…Preservatives, CA and BA not only maintained low pH but also reduced PPO activity thus preventing browning of the juice. At low pH, the undissociated benzoic acid accumulates on the cell membranes or on various structures and surfaces of the bacterial and fungal cells, effectively inhibiting their cellular activity (21,(25)(26)(27). Hence the shelf life of the juice was prolonged up to 90 days.…”
Section: Resultsmentioning
confidence: 98%
“…According to previous research, the increase of alcohol content tended to suppress the dissociation of carboxylic acid in alcohol–water mixtures, which resulted in the decline of carboxylate ions in the mixtures. This might cause a decrease of the modifiers adsorbed on the surface of α-HH.…”
Section: Resultsmentioning
confidence: 81%