Rate constants for the removal of O bΣ by collisions with species relevant to combustion, H, CO, NO, CH and CH have been measured in the temperature range 297-800 K. O(bΣ) was produced from ground-state molecular oxygen by photoexcitation pulses from a tunable dye laser, and the deactivation kinetics were followed by observing the temporal behavior of the bΣ-XΣ fluorescence. The removal rate constants for H, CO, NO, CH, and CH could be represented by the modified Arrhenius expressions k = (1.44 ± 0.02) × 10 T exp[(0 ± 10)/ T], k = (6.9 ± 0.4) × 10 T exp[(939 ± 33)/ T], k = (2.63 ± 0.14) × 10 T exp[(590 ± 26)/ T], k = (3.5 ± 0.2) × 10 T exp[(-220 ± 24)/ T], and k = (2.34 ± 0.10) × 10 T exp[(680 ± 16)/ T] cm molecule s, respectively. All of the rate constants measured at room temperature were found to be in good agreement with previously reported values, whereas the values at elevated temperatures up to 800 K were systematically measured for the first time.