Dissociative Recombination Chemistry and Plasma Dynamics

Continetti, Robert E.

doi:10.21236/ada483644

Cited by 2 publications

(2 citation statements)

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“…Thus, particularly interesting are the recent experimental studies of Deyerl and Continetti 33 and Continetti 34 in which electron and neutral fragments are detected in coincidence. However, after combining them, the total angular resolved spectra obtained in the diabatic and adiabatic representations are of similar quality, showing that these quantities are not very sensitive to the nonadiabatic effects arising near conical intersections.…”

Section: Discussionmentioning

confidence: 99%

“…[28][29][30] In one side, Neumark published 31 the photoelectron detachment spectra recorded some years before 32 at two geometries with respect to the polarization vector of the incident light. Second, Deyerl and Continetti 33 and Continetti 34 have detected in coincidence the electron and neutral fragments. Moreover, since the initial wave packet is sitting on the top of the two conical intersections, see Fig.…”

Section: Introductionmentioning

confidence: 94%

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Coupled diabatic potential energy surfaces for studying the nonadiabatic dynamics at conical intersections in angular resolved photodetachment simulations of OHF−→OHF+e−

Gómez-Carrasco

Aguado

Paniagua

et al. 2006

The Journal of Chemical Physics

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An energy-based method is proposed for the diabatization of the OH(2Pi)+F(2P)-->O(3P)+HF(1Sigma+) reaction. It is demonstrated that the diabatic representation obtained is regularized, i.e., the residual derivative couplings do not present singularities at the conical intersections appearing along the reaction path. This method only requires the knowledge of the 1,2 3A" and 1 3A' eigenvalues and does not require any adjustable parameter. Thus, many convergence problems arising in other derivative-based diabatization methods are avoided, and the description of the configuration space along the reaction path is enormously simplified. Three-dimensional coupled diabatic energy surfaces are obtained by an interpolation procedure using approximately 4000 accurate ab initio points. The angular resolved photodetachment cross sections are obtained in the diabatic and adiabatic representations using a wave packet method. An excellent agreement is obtained with recent experimental data [D. M. Neumark, Phys. Chem. Chem. Phys. 7, 433 (2005)] for high electron kinetic energies where only the triplet electronic states contribute.

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Section: Discussionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 94%

Coupled diabatic potential energy surfaces for studying the nonadiabatic dynamics at conical intersections in angular resolved photodetachment simulations of OHF−→OHF+e−

Gómez-Carrasco

Aguado

Paniagua

et al. 2006

The Journal of Chemical Physics

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The Judicial Genealogy (and Mythology) of John Roberts: Clerkships from Gray to Brandeis to Friendly to Roberts

Snyder¹

2010

SSRN Journal

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During his Supreme Court nomination hearings, John Roberts idealized and mythologized the first judge he clerked for, Second Circuit Judge Henry Friendly, as the sophisticated judge-as-umpire. Thus far on the Court, Roberts has found it difficult to live up to his Friendly ideal, particularly in several high-profile cases. This Article addresses the influence of Friendly on Roberts and judges on law clerks by examining the roots of Roberts's distinguished yet unrecognized lineage of former clerks: Louis Brandeis 's clerkship with Horace Gray, Friendly's clerkship with Brandeis, and Roberts's clerkships with Friendly and Rehnquist. Labeling this lineage a judicial genealogy, this Article reorients clerkship scholarship away from clerks' influences on judges to judges' influences on clerks. It also shows how Brandeis, Friendly, and Roberts were influenced by their clerkship experiences and how they idealized their judges. By laying the clerkship experiences and career paths of Brandeis, Friendly, and Roberts side-byside in detailed primary source accounts, this Article argues that judicial influence on clerks is more professional than ideological and that the idealization ofjudges and emergence of clerks hips as must-have credentials contribute to a culture ofjudicial supremacy.

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Dissociative Recombination Chemistry and Plasma Dynamics

Cited by 2 publications

References 6 publications

Coupled diabatic potential energy surfaces for studying the nonadiabatic dynamics at conical intersections in angular resolved photodetachment simulations of OHF−→OHF+e−

Coupled diabatic potential energy surfaces for studying the nonadiabatic dynamics at conical intersections in angular resolved photodetachment simulations of OHF−→OHF+e−

The Judicial Genealogy (and Mythology) of John Roberts: Clerkships from Gray to Brandeis to Friendly to Roberts

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