“…Commonly, halogens are coupled in a charge‐complex[ 34 , 38 , 39 , 40 , 41 , 42 , 43 , 44 , 45 , 46 ] (Figure 1 , c) with various S ‐donor ligands, in particular, dithiooxamides,[ 38 , 39 , 40 , 41 , 42 ] dithiocarbamates,[ 42 , 43 , 44 ] thiourea[ 44 , 45 ] and thioimidophosphinic acid [46] compounds. The latter then stabilize Au III and Au I centres in THF,[ 38 , 39 , 40 , 41 ] MeCN,[ 41 , 47 , 48 ] DCM,[ 45 , 48 ] chloroform, [39] DMSO, [49] acetone,[ 41 , 42 , 43 ] MEK, [41] Et 2 O,[ 44 , 46 ] ionic liquids,[ 50 , 51 ] deep eutectic solvent, [52] or even in water. [34] Similar to aqueous iodine‐iodine leaching, over stoichiometric amounts of halogen are needed for quantitative dissolution of Au.…”